Current Issue : April-June Volume : 2022 Issue Number : 2 Articles : 5 Articles
Boron nitride (BN) is primarily a synthetically produced advanced ceramic material. It is isoelectronic to carbon and, like carbon, can exist as several polymorphic modifications. Microwave plasma chemical vapor deposition (MPCVD) of metastable wurtzite boron nitride is reported for the first time and found to be facilitated by the application of direct current (DC) bias to the substrate. The applied negative DC bias was found to yield a higher content of sp3 bonded BN in both cubic and metastable wurtzite structural forms. This is confirmed by X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR). Nano-indentation measurements reveal an average coating hardness of 25 GPa with some measurements as high as 31 GPa, consistent with a substantial fraction of sp3 bonding mixed with the hexagonal sp2 bonded BN phase....
Carbon fiber reinforced polymer (CFRP) composites are integral to today’s industries. Curing or consolidation are vital processes for manufacturing CFRP components. Microwave processing has many advantages compared with conventional processing technologies using ovens or autoclaves; however, the uneven temperature distribution caused by the non-uniform microwave field has a significant influence on the quality of the cured products. In this study, we propose a new idea to solve this problem, i.e., limiting the absorption of hot areas. Under such circumstances, cold ones can catch up with them more easily. To adjust the absorbing capability of the CFRP laminate, periodically arranged metallic resonance structures supported by a dielectric spacer are introduced on its surface. The dielectric spacer, made of epoxy matrix and strontium titanate particles, is designed to possess a dielectric constant positively related to temperatures. In this situation, the microwave absorption (2.45 GHz) of the metal-dielectric-CFRP configuration is changed from 97.6% at room temperature to 55.9% at 150 C continuously. As a result, a reduction of 43.1% in maximum temperature difference and 89% in standard deviation has been achieved....
Laminar burning velocity of lean methane/air flames exposed to pulsed microwave irradiation is determined experimentally as part of an effort to accurately quantify the enhancement resulting from exposure of the flame to pulsed microwaves. The experimental setup consists of a heat flux burner mounted in a microwave cavity, where the microwave has an average power of up to 250 W at an E-field in the range of 350–380 kV/m. Laminar burning velocities for the investigated methane/air flames increase from 1.8 to 12.7% when exposed to microwaves. The magnitude of the enhancement is dependent on pulse sequence (duration and frequency) and the strength of the electric field. From the investigated pulse sequences, and at a constant E-field and average power, the largest effect on the flame is obtained for the longest pulse, namely 50 s. The results presented in this work are, to the knowledge of the authors, the first direct determination of laminar burning velocity on a laminar stretch-free flame exposed to pulsed microwaves....
,is paper introduces the innovative technique to release the bursting liability of coal seam via microwave irradiation. To verify the feasibility of this environment-friendly technique, a series of laboratory tests incorporating acoustic emission (AE) investigation were carried out. Test results indicated that both the uniaxial compressive strength (UCS) and bursting energy index of raw and water-soaked coal samples were significantly reduced. In particular, the bursting liability was reduced by one level when the values of UCS were compared, the evidence of which is the variation of wave velocities of tested coal samples. It can also be found from the events and hits in the complete stress-strain curve and the cumulative curve of acoustic emission that the elastic modulus of the raw and water-soaked coal samples subjected to microwave irradiation decreased by 58.42% and 29.63%, respectively. ,is facilitates the entry into the stage of stable crack propagation more quickly, the growth rate and size of the cracks were slower and more uniform, and there were no smaller coal fragments ejecting during the failure process of the coal samples. Meanwhile, the proportion of high-energy events released in coal samples experienced a decline after the treatment of the microwave. Moreover, microwave heating principally promoted the initiation and expansion of microcracks in coal samples under the influence of microwave power of 1kW and a heating time of 120s, which may cause the overall damage of large fractures to break into multiple small and medium cracks. Based on the experimental results, the conceptual process of using microwave in weakening the bursting liability of coal seam was then proposed, which will be the meaningful reference for microwave-assisted oil recovery and coal bed methane production....
In this study, we present a strategy for valorizing lignocellulosic wastes (licorice root and willow bark) that result from industrial extraction of active principles using water as green solvent and aqueous NaOH solution. The wastes were submitted to severe ultrasound (US) and microwave (MW) treatments. The aim of these treatments was to extract the remaining active principles (using water as a solvent) or to prepare them for cellulose enzymatic hydrolysis to hexoses (performed in an NaOH aqueous solution). The content of glycyrrhizic acid and salicin derivatives in licorice root and willow bark wastes, respectively, were determined. The best results for licorice root were achieved by applying the US treatment for 5 min at 25 C (26.6 mg glycyrrhizic acid/gDM); while, for willow bark, the best results were achieved by applying the MW treatment for 30 min at 120 C (19.48 mg salicin/gDM). A degradation study of the targeted compounds was also performed and showed good stability of glycyrrhizic acid and salicin derivatives under US and MW treatments. The soluble lignin concentration prior to enzymatic hydrolysis, as well as the saccharide concentration of the hydrolyzed solution, were determined. As compared with the MW treatment, the US treatment resulted in saccharides concentrations that were 5% and 160% higher for licorice root and willow bark, respectively....
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